Head to Head
| ATP Banja Luka | 2023/04/19 14:00 | Alexei Popyrin v Alex Molcan | 6-7,6-4,5-7 |
Home History
| The Boodles | 2023/06/27 15:00 | Borna Coric v Alexei Popyrin | 6-4,3-6,0-0 |
| ATP Queen's | 2023/06/20 13:25 | Jordan Thompson v Alexei Popyrin | 6-4,6-4 |
| ATP Queen's | 2023/06/18 10:00 | Arthur Fils v Alexei Popyrin | 5-7,7-6,7-6 |
| ATP Queen's | 2023/06/17 11:20 | Arthur Fery v Alexei Popyrin | 6-7,6-3,3-6 |
| ATP Hertogenbosch | 2023/06/15 09:00 | Tallon Griekspoor v Alexei Popyrin | 6-3,6-2 |
| ATP Hertogenbosch | 2023/06/13 12:30 | Arthur Rinderknech v Alexei Popyrin | 3-6,6-7 |
| Challenger Surbiton | 2023/06/06 12:50 | Alexei Popyrin v Luke Saville | 7-6,4-6,6-7 |
| French Open | 2023/05/29 10:40 | Alexei Popyrin v Aslan Karatsev | 3-6,7-6,1-6,2-6 |
Away History
| Challenger Bratislava | 2023/06/17 13:25 | Alex Molcan v Dimitar Kuzmanov | 0-6,1-6 |
| Challenger Bratislava | 2023/06/16 15:30 | Alex Molcan v Tomas Machac | 7-6,3-6,6-1 |
| Challenger Bratislava | 2023/06/15 14:30 | Alex Molcan v Kimmer Coppejans | 6-4,7-5 |
| Challenger Bratislava | 2023/06/13 15:50 | Alex Molcan v Roman Andres Burruchaga | 4-6,6-2,6-3 |
| French Open | 2023/06/01 18:15 | Alexander Zverev v Alex Molcan | 6-4,6-2,6-1 |
| French Open | 2023/05/30 10:25 | Hugo Gaston v Alex Molcan | 1-6,6-7,4-6 |
| ATP Róma | 2023/05/13 09:30 | Andrey Rublev v Alex Molcan | 6-3,6-4 |
| ATP Róma | 2023/05/11 17:15 | Stefano Napolitano v Alex Molcan | 4-6,6-3,6-7 |